Chuck Bass and Blair Waldorf – Gossip Girl (The CW)
From the very first episode, the chemistry between these two has been off the charts. She’s the Queen Bee – pretty, popular and smart; He’s the misunderstood bad boy – selfish, arrogant and prone to making bad choices. But when it boils down to it, Chuck and Blair have an undeniable connection. They’re both a little lost and completely determined to be the best. They’ve hurt each other countless times but their love has only gotten stronger, even when they’re apart. They’ve each proven time and time again that nothing and no one is more important than the love they feel for each other.